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▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
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성 분 명 |
Dihydrochelerythrine |
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다른이름들 |
Dihydrotoddaline
Toddalinine
12,13-Dihydroxy-1,2-dimethoxy-12-methyl[1,3]benzodioxolo[5,6-c]-phenanthridine |
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함유 천연물 |
Chelidonium majus L.[]() |
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분 자 식 |
C21H19NO4 |
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화학족 분류 |
알칼로이드(alkaloid); |
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분 자 량 |
349.39 |
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녹 는 점 |
169-171°C C6H6 |
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UV_CHART |
(λmax, nm) (EtOH):227(4.53), 282(4.65), 318(4.18), 350 sh(3.52) |
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HNMR_CHART |
(CDCl3,100 MHz) δ:7.71(1H, s, H1), 7.10(1H, s, H4), 7.47(1H, d, 8, H5), 7.69(1H, d, 8, H6), 4.28(1H, s, H8), 6.92(1H, d, 8, H11), 7.50(1H, d, 8, H12), 2.56(3H, s, NMe), 3.88(3H, s, 9-OMe), 3.84(3H, s, 10-OMe), 6.01(2H, s, OCH2O) |
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MASS_CHART |
M+= 349, m/z= 348, 247, 333, 332, 318, 305, 304, 290 |
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참고문헌 |
· BD. Krane et al., J. Nat. Prod., 47, 1, 1984
· L. Slavikova et al., Chem. Listy, 49, 1546, 1955; CA, 50, 4990h
· TR. Govindachari et al., J. Chem. Soc., 769, 1956
· PJ. Scheuer et al., J. Org. Chem., 27, 1472, 1962
· PD. Desai et al., Indian J. Chem., 5, 41, 1967
· M. Onda et al., Chem. Pharm. Bull., 18, 1435, 1970 (pmr)
· N. Weber, Chem. Ber., 106, 3769, 1973
· BA. Dadson et al., J. Chem. Soc. Perkin Trans. 1, 146, 1976
· J. Slavik et al., Coll. Czech. Chem. Comm., 42, 2686, 1976
· FY. Chou et al., Heterocycles, 7, 969, 1977
· AI. Gray et al., Phytochemistry, 16, 1017, 1977
· JA. Swinehart et al., Phytochemistry, 19, 1219, 1980
· KhSh. Khusainova et al., Khim. Prir. Soedin., 17, 670, 1981; CA, 96, 65673y
· SM. Oechslin et al., J. Nat. Prod., 54, 519, 1991 |
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