코스넷:::::화장품원료:::::

 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

Chelilutine

다른이름들 

1,2,4-Trimethoxy-12-methyl[1,3]benzodioxolo[5,6-c]phenanthridinium

함유 천연물 

Chelidonium majus L.[]()

분 자 식 

C₂₂H₂₀NO₅

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

378.408

녹 는 점 

(as Cl) 229-230°C

UV_CHART 

(λmax, nm) (EtOH):(as Cl); 230(4.45), 241 sh(4.39), 280.5(4.56), 340(4.29), 420sh(3.41), 470(3.55)

HNMR_CHART 

(DMSO-d6,60 MHz) δ:(psi-CN); 7.57(1H, s, H1), 7.35(1H, s, H4), 7.63(1H, d, 8, H5), 8.33(1H, d, 8, H6), 6.96(1H, s, H11), 5.88(1H, s, H8), 6.18(2H, s, OCH2O), 2.56(3H, s, NMe), 3.98(3H, s, 12-OMe), 3.85(3H, s, 10-OMe), 3.85(3H, s, 9-OMe)

참고문헌 

· BD. Krane et al., J. Nat. Prod., 47, 1, 1984(uv,ir,pmr) · J. Slavik et al., Coll. Czech. Chem. Comm., 25, 1667, 1960; 33, 1619, 1968 · C. Hruban et al., Coll. Czech. Chem. Comm., 35, 3420, 1970(uv) · H. Ishii et al., Chem. Pharm. Bull., 25, 3120, 1977; 26, 864, 1978 · M. Hanaoka et al., Chem. Pharm. Bull., 37, 857, 1989