|
|
 |
▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
|
|
|
성 분 명 |
9-beta-Hydroxylamprolobine |
|
|
|
다른이름들 |
Lamprolobine ((+)-form); 9beta-Hydroxy
5-(Glutarimidomethyl)quinolizidine; 9beta-Hydroxy
1-[(Octahydro-2H-quinolizin-1-yl)methyl]-2,6-piperidinedione; 9beta-Hydroxy |
|
함유 천연물 |
Sophora velutina var. zimbabweensis[-]() |
|
분 자 식 |
C15H24N2O3 |
|
화학족 분류 |
알칼로이드(alkaloid); |
|
분 자 량 |
280.37 |
|
굴 절 율 |
[α]D = +24°(EtOH) |
|
HNMR_CHART |
(CDCl3) δ:1.05(H-4), 1.34(H-7), 1.23(H-8), 1.62(H-4), 1.46(H-3), 1.62(H-3), 3.78(H-9), 1.62(H-6), 1.68(H-5), 2.07(H-7), 2.07(H-8), 1.95(H-15), 1.95(H-10), 2.65(H-14), 2.80, 3.02(H-10), 3.67(H-11), 3.76(H-11) |
|
CNMR_CHART |
(CDCl3) δ: 56.2, 24.3, 28.0, 39.3, 66.6, 27.7, 33.6, 65.5, 63.1, 41.7, 172.8, 33.1, 17.4, 33.1, 172.8 |
|
MASS_CHART |
M+= 280, m/z= 263, 262, 168, 154, 126, 113, 99 |
|
참고문헌 |
· K. Asres et al., J. Nat. Prod., 49, 117, 1986(ir,pmr,cmr,ms)
· NK. Hart et al., Aust. J. Chem., 21, 1619, 1968(ir,ms)
· Y. Yamada et al., Agric. Biol. Chem., 34, 1536, 1970
· SI. Goldberg et al., J. Org. Chem., 35, 242, 1970
· E. Wenkert et al., J. Org. Chem., 35, 515, 1970
· WJ. Keller, Phytochemistry, 19, 2233, 1980
· I. Murakoshi et al., Phytochemistry, 20, 1725, 1981
· WJ. Keller, J. Nat. Prod., 44, 357, 1981
· JP. Michael et al., Tetrahedron, 48, 10211, 1992 |
|
|
|
|
|
