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▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
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성 분 명 |
Violaxanthin (all-E form) |
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다른이름들 |
Violeaxanthin (all-E form)
Zeaxanthin diepoxide (all-E form)
5,6,5',6'-Diepoxy-5,5',6,6'-tetrahydro-beta,beta-cartene-3,3'-diol (all-E form) |
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함유 천연물 |
Brassica juncea (L.) Czern. var. juncea[갓(Gat)](개채(芥菜)) Brassica juncea var. crispifolia L.H.Bailey[겨자(Gyeo-ja)](백개자(白芥子)) Brassica oleracea var. capitata L.[양배추(Yang-bae-chu)]() Citrus aurantium var. daidai Makino[광귤(Gwang-gyul)](대대화(玳玳花),지실(枳實)) Citrus junos Siebold ex Tanaka[유자나무(Yu-ja-na-mu)](유자(柚子),유피(柚皮),등자피(橙子皮)) Citrus sinensis (L.) Osbeck[당귤나무(Dang-gyul-la-mu)](기실(枳實)) Diospyros kaki Thunb.[감나무](시체(枾체),시자(枾子),시엽(枾葉),시병(枾餠),건시(乾枾),백시(白枾),상시(霜枾),시상(枾霜),시화(枾花),오시(烏枾),홍시(烘枾),화시(火枾)) Equisetum hyemale L.[속새(Sok-sae)](목적(木賊)) Euonymus japonicus Thunb.[사철나무(Sa-cheol-na-mu)](조경초(調經草)) Ginkgo biloba L.[은행나무(Eun-haeng-na-mu)](은행엽(銀杏葉),백과(白果)) Glycine max (L.) Merr.[콩(Kong)](흑대두(黑大豆),담두시(淡豆시),대두황권(大豆黃卷)) Helianthus annuus L.[해바라기(Hae-ba-ra-gi)](향일규자(向日葵子),향일규화탁(向日葵花托),향일규엽(向日葵葉),향일규화(向日葵花)) Impatiens nolitangere L. var. nolitangere[노랑물봉선(No-rang-mul-bong-seon)](야봉선화(野鳳仙花)) Leonurus japonicus Houtt.[익모초(Ik-mo-cho)](익모초(益母草),충위자(충위子)) Medicago sativa L.[자주개자리(Ja-ju-gae-ja-ri)]() Panax ginseng C.A.Mey.[인삼(In-sam)](인삼(人蔘),산삼(山蔘),장뇌(樟腦),인삼엽(人蔘葉),인삼로(人蔘蘆),미삼(尾蔘),인삼자(人蔘子),홍삼(紅蔘)) Parmelia saxatilis Ach.[-](지의(地衣)) Raphanus sativus L.[무(Mu)](나복자(蘿蔔子),나복(蘿蔔),나복엽(蘿蔔葉),나복근(蘿蔔根),내복자(萊복子)) Rosa rugosa Thunb. var. rugosa[해당화(Hae-dang-hwa)](매괴화(매괴花),매괴화근(매괴花根)) Viola tricolor L.[삼색제비꽃(Sam-saek-je-bi-kkot)]() Vitis vinifera L.[포도(Po-do)](포도(葡萄),포도근(葡萄根),포도경엽(葡萄莖葉),포도엽(葡萄葉)) Zea mays L.[옥수수(Ok-su-su)](옥미수(玉米鬚)) |
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분 자 식 |
C40H56O4 |
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화학족 분류 |
테트라테르페노이드(tetraterpenoid); |
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분 자 량 |
600.89 |
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녹 는 점 |
red 208°C MeOH |
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굴 절 율 |
[α]20 D = +38°( CHCl3) |
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UV_CHART |
(λmax, nm) (benzene):483, 453, 426 |
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HNMR_CHART |
(Py-d5,300 MHz) δ:6.17(H7), 6.66(H8), 6.37(H10), 6.86(H11), 6.63(H12), 6.48(H14), 6.85(H15), 1.26(Me-16), 1.16(Me-17), 1.29(Me-18), 2.04(Me-19), 2.02(Me-20), 6.17(H7'), 6.66(H8'), 6.37(H10'), 6.86(H11'), 6.63(H12'), 6.48(H14'), 6.85(H15'), 1.26(Me-16') |
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CNMR_CHART |
δ: 35.4(C1), 47.2(C2), 64.1(C3), 40.9(C4), 67.3(C5), 70.4(C6), 123.9(C7), 137.2(C8), 134.2(C9), 132.4(C10), 124.6(C11), 138.2(C12), 136.4(C13), 132.9(C14), 130.2(C15), 24.7(1-Me), 29.7(1-Me), 20.0(5-Me), 12.8(9-Me), 13.1(13-Me) |
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참고문헌 |
· P. Molnar et al., Phytochemistry, 25, 195, 1986(uv,pmr)
· GM. Fishman et al., Chem. Nat. Compd., 24, 3, 395, 1988
· S. Takagi, Agric. Biol. Chem., 49, 4, 1211, 1985
· GP. Moss, Pure Appl. Chem., 47, 97, 1976(cmr)
· AA. Kolesnik et al., Chem. Nat. Compd., 20, 1, 110, 1984 |
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