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▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
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성 분 명 |
Senkyunolide C |
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다른이름들 |
5-Hydroxybutylidenephthalide
3-Butylidene-1(3H)-isobenzofuranone; (Z)-form, 5-Hydroxy
3-Butylidenephthalide; (Z)-form, 5-Hydroxy |
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함유 천연물 |
Cnidium officinale Makino[천궁(Cheon-gung)](천궁(川芎),강리(江籬),궁궁(芎궁),무궁(撫芎),작뇌궁(雀腦芎))
Ligusticum chuanxiong Hort.[](궁궁(芎궁)) |
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분 자 식 |
C12H12O3 |
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화학족 분류 |
알파-피론(alpha_pyrone); |
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분 자 량 |
204.228 |
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녹 는 점 |
95-100°C |
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굴 절 율 |
[α]D = 0°(C 0.67, CHCl3) |
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UV_CHART |
(λmax, nm) (EtOH):228(9100), 256(19300) |
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HNMR_CHART |
(CDCl3,200 MHz) δ:0.98(3H,t,7.3,H11), 1.54(2H,sext,7.3,H10), 2.43(2H,dt,7.8,7.3,H9), 5.59(1H,t,7.8), 7.00(1H,dd,8.3,2.4), 7.05(1H,d,2.4), 7.76(1H,d,8.3) |
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MASS_CHART |
M+= 204, m/z= 175(100), 162, 147, 119, 91 |
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참고문헌 |
· T. Naito et al., Phytochemistry, 31, 2, 639, 1992
· M. Fujita et al., Chem. Pharm. Bull., 32, 9, 3770, 1984; 35, 4, 1427, 1987(uv,ir,pmr,ms)
· S. Berlingozzi et al., Gazz. Chim. Ital., 57, 255, 1927
· H. Mitsuhashi et al., Chem. Pharm. Bull., 8, 243, 1960
· SK. Banerjee et al., Annalen, 699, 1982
· DLJ. Opdyke et al., Food Chem. Toxicol., 21, 659, 1983
· M. Puech-Baronnet et al., Planta Med., 50, 105, 1984
· Y. Ogawa et al., Synth. Commun., 22, 315, 1992 |
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