코스넷:::::화장품원료:::::

 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

Rhombifoline ((-)-form)

다른이름들 

N-(3-Butenyl)cytisine

함유 천연물 

Sophora chrysophylla Seem.[-]()
Sophora flavescens Solander ex Aiton[고삼(Go-sam)](고삼(苦蔘),고삼실(苦蔘實),수괴(水槐),지괴(地槐))
Sophora franchetiana Dunn[-]()
Sophora microphylla[-]()
Sophora mollis[-]()
Sophora seudiflora[-]()

분 자 식 

C₁₅H₂₀N₂O

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

244.339

녹 는 점 

yellowish oily°C

굴 절 율 

[α]25 D = -232.4° (C 2.13,EtOH)

HNMR_CHART 

(C6D6,100 MHz) δ:1.08(2H,m,H8), 1.5-2.1(7H,m), 2.19(1H,br s,H7), 2.38(1H,br d,9.5,H11 or 13 eq.), 2.48(1H,br d,9.5,H11 or 13 eq.), 3.69(1H,dd,15.5,7.5, H10a), 4.05(1H,d,15.5,H10b), 4.82(1H,fine split d,17,H17), 4.87(1H,fine split d,9.5,H17'), 5.39(1H,dd,6.5,1.5,H5), 5.48(1H,m,H16), 6.53(1H,dd,6.5,1.5,H5), 5.48(1H,m,H16), 6.53(1H,dd,9.5,1.5,H5), 6.81(1H,dd,9.5,6.5,H4)

MASS_CHART 

M+= 244, m/z= 203(100), 160, 146, 98, 58

참고문헌 

· S. Ohmiya et al., Phytochemistry, 20, 8, 1997, 1981(pmr,ms) · RHF. Manske et al., Can. J. Res., Sect. B, 21, 144, 1943 · WF. Cockburn et al., Can. J. Chem., 30, 92, 1952