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▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
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성 분 명 |
PF-P |
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다른이름들 |
Pueraria compound PF-P
N(a)-bera-D-Glucopyranosyl-N(b)-hexanoyltryptophan
1-beta-D-Glucopyranosyl-N-hexanoyltryptophan
N-Acyl-N(1)-glucosyltryptophan
1-Glucosyl-11-N-carproyltryptophan |
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함유 천연물 |
Pueraria lobata (Willd.) Ohwi[칡(Chik)](갈근(葛根))
Solanum nigrum L. var. nigrum[까마중(Kka-ma-jung)](용규(龍葵),용규자(龍葵子)) |
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분 자 식 |
C23H32N2O8 |
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화학족 분류 |
알칼로이드(alkaloid); |
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분 자 량 |
464.52 |
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녹 는 점 |
amorphous°C |
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굴 절 율 |
[α]20 D = +19.7° (C 0.5,DMSO) |
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UV_CHART |
(λmax, nm) :223(25800), 273(5500), 279(5400), 290(4300) |
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HNMR_CHART |
(DMSO-d6+D2O) δ:2.00(2H,t,H2''), 1.42(2H,q,H3''), 1.18(2H,m,H4''), 1.23(2H,m,H5''), 0.83(3H,t,H6''), 5.35(1H,d,H1'), 3.78(1H,t,H2'), 3.42-3.48(3H,m,H3',5',6'a), 3.67(1H,d,H6'b), near 3.27(H4'), 7.19(1H,s,H2), 7.45(1H,d,H4), 6.97(1H,t,H5), 7.08(1H,t,H6), 7.45(1H,d,H7), 3.01(1H,dd,H10a), 3.20(1H,dd,H10b), 4.26(1H,dd,H11) |
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CNMR_CHART |
(DMSO-d6) δ: 171.2, 35.5, 24.8, 30.9, 21.8, 13.7, 84.1, 70.9, 77.7, 70.1, 78.9, 61.0, 123.7, 111.5, 118.5, 118.7, 120.7, 110.0, 129.2, 136.3, 26.9, 54.6, 174.9 |
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MASS_CHART |
FABm/z= 965, 947, 927, 501, 485, 463 |
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참고문헌 |
· T. Nohara et al., Chem. Pharm. Bull., 36, 10, 4171, 1988(uv,ir,nmr,ms)
· Y. Niho et al., Yakugaku Zasshi, 110, 8, 604, 1990
· JR. Spies, J. Am. Chem. Soc., 70, 3717, 1948
· JS. Fitzgerald et al., Aust. J. Chem., 16, 246, 1963
· S. Ghosal et al., Phytochemistry, 10, 195, 3312, 1971
· N. Mandava et al., Phytochemistry, 13, 2853, 1974
· W. Kulik et al., Biomed. Mass Spectrom., 15, 419, 1988
· H. Eto et al., Bull. Chem. Soc. Jpn., 62, 961, 1989
· B. Rzesztarska et al., Org. Prep. Proced. Int., 22, 655, 1990
· RS. Phillips et al., J. Het. Chem., 29, 1181, 1992 |
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