코스넷:::::화장품원료:::::

 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

Oxysanguinarine

다른이름들 

Alkaloid C 13-Methyl[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridin-14(3H)-one 5-Methyl-2,3;7,8-bis(methylenedioxy)benzo[c]phenanthridin-6(5H)-one

함유 천연물 

Chelidonium majus L.[]()
Papaver somniferum L.[양귀비(Yang-gwi-bi)](앵속각(罌粟殼))

분 자 식 

C₂₀H₁₃NO₅

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

347.33

녹 는 점 

300-308(dec.)°C

UV_CHART 

(λmax, nm) (EtOH):241(4.27), 281 sh(4.61), 289(4.70), 331(4.17), 348(4.18), 370(4.06), 385(4.02)

HNMR_CHART 

(CDCl3,90 MHz) δ:3.9(3H, s, NMe), 6.11 & 6.28(ea.1H, s, OCH2O), 7.17-8.15(6H, aromatic protons)

MASS_CHART 

M+= 347, m/z= 347(100), 346, 318, 289, 203, 159, 69, 44

참고문헌 

· VB. Pandey et al., Phytochemistry, 18, 695, 1979(uv,ir,pmr,ms) · BD. Krane et al., J. Nat. Prod., 47, 1, 1984(uv,ir,pmr,ms) · RHF. Manske, Can. J. Res., Sect. B, 21, 140, 1943 · XA. Dominguez et al., Can. J. Chem., 43, 679, 1965 · DB. MacLean et al., Can. J. Chem., 47, 1951, 1969 · A. Ikuta et al., Phytochemistry, 13, 2175, 1974 · J. Slavik et al., Coll. Czech. Chem. Comm., 42, 2686, 1977 · M. Shamma et al., J. Org. Chem., 43, 2852, 1978 · J. Smidrkal., Coll. Czech. Chem. Comm., 49, 1412, 1984