|
|
▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
|
|
|
성 분 명 |
Norsanguinarine |
|
|
|
다른이름들 |
[1,3]Benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine
2,3;7,8-Bis(methylenedioxy)benzo[c]phenanthridine |
|
함유 천연물 |
Chelidonium majus L.[]() Papaver somniferum L.[양귀비(Yang-gwi-bi)](앵속각(罌粟殼)) |
|
분 자 식 |
C19H11NO4 |
|
화학족 분류 |
알칼로이드(alkaloid); |
|
분 자 량 |
317.304 |
|
녹 는 점 |
pale-yell. 285-287°C CHCl3/MeOH |
|
UV_CHART |
(λmax, nm) (EtOH):212(4.33), 243(4.67), 251 sh.(4.50), 275 sh.(4.50), 281(4.55), 293 sh.(4.41), 328(4.22), 341(4.00), 3.82(3.60), 399(3.65) |
|
HNMR_CHART |
(TFA-d,60 MHz) δ:7.94(1H, s, H1), 7.42(1H, s, H4), 8.47(1H, d, 10, H5), 8.15(1H. d, 10, H6), 9.51(1H, s, H8), 7.92(1H. d, 8, H11), 8.45(1H, d, 8, H12), 6.25(2H, s, OCH2O), 6.50(2H, s, OCH2O) |
|
MASS_CHART |
M+= 317, m/z= 261, 260, 259, 204, 203, 202, 201, 175, 101(100) |
|
참고문헌 |
· T. Furuya et al., Phytochemistry, 11, 3041, 1972(uv,ir,pmr,ms)
· BD. Krane et al., J. Nat. Prod., 47, 1, 1984(uv,ir,pmr,ms)
· K. Haisova et al., Coll. Czech. Chem. Comm., 38, 3312, 1973
· A. Ikuta et al., Phytochemistry, 13, 2175, 1974
· K. Haisova et al., Coll. Czech. Chem. Comm., 40, 1576, 1975
· A. Ikuta et al., Phytochemistry, 15, 577, 1976
· W. Dopke et al., Z. Chem., 16, 54, 1976
· H. Itokawa et al., Phytochemistry, 17, 839, 1978
· L. Castedo et al., Tetrahedron Lett., 2923, 1978
· B. Sener et al., Phytochemistry, 22, 2073, 1983 |
|
|
|
|