HNMR_CHART |
(CDCl3,400 MHz) δ:0.85(3H, s, 1'beta-Me), 1.00(3H, s, 1'alpha-Me), 1.31(1H, d, 7, 3'-OH), 1.34(1H, d, 5, 3-OH), 1.37(1H, dd, 13.2, 7, H2'), 1.48(1H, t, 12, H2beta), 1.63(3H, br s, 5'-Me), 1.74(3H, s, 5-Me), 1.77(1H, ddd, 12.5, 4, 2, H2alpha), 1.90(3H, s, 9'-Me), 1.97(9H, br s, 9,13,13'-Me), 2.04(1H, br dd, 17, 10, H4beta), 2.38(1H, m, H4alpha), 2.41(1H, H6'alpha), 4.00(1H, m, H3), 4.35(1H, m, H3'), 5.43(1H, dd, 15.3, 9.5, H7'), 5.55(1H, br s, H4'), 6.11(1H, d, 16, H7), 6.13(2H, ea. d, 16, H8,8'), 6.14, 6.16(2H, ea. d, H10',10), 6.26(2H, m, H14,14'), 6.36(2H, ea. d, 15, H12',12), 6.61-6.64(4H, m, H11',15,15',11) |
CNMR_CHART |
(CDCl3 + DMSO-d6) δ: 36.76, 48.41, 64.34, 42.61, 126.69, 137.26, 125.81, 137.92, 135.48, 131.03, 124.88, 137.27, 136.09, 132.44, 129.99, 28.63, 30.27, 21.55, 12.61, 12.68, 34.00, 44.89, 63.46, 125.97, 135.55, 54.77, 129.13, 137.35, 134.88, 130.52, 124.80, 137.27, 136.1 |
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