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▣ 천연물에서 분리된 개별유효성분 레코드 등록정보 |
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성 분 명 |
Lamprolobine ((+)-form) |
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다른이름들 |
5-(Glutarimidomethyl)quinolizidine
1-[(Octahydro-2H-quinolizin-1-yl)methyl]-2,6-piperidinedione |
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함유 천연물 |
Sophora chrysophylla Seem.[-]()
Sophora velutina var. zimbabweensis[-]() |
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분 자 식 |
C15H24N2O2 |
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화학족 분류 |
알칼로이드(alkaloid); |
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분 자 량 |
264.371 |
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굴 절 율 |
[α]D = +29°(C 1.5, EtOH) |
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HNMR_CHART |
(CDCl3) δ:1.01(H-4), 1.23(H-7), 1.28(H-8), 1.42(H-4), 1.55(H-3), 1.58(H-3), 1.60(H-9), 1.65(H-9), 1.68(H-6), 1.74(H-5), 1.78(H-7), 1.91(H-8), 1.91(H-15), 2.01(H-10), 2.63(H-14), 2.77, 2.83(H-10), 3.67(H-11), 3.77(H-11) |
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CNMR_CHART |
(CDCl3) δ: 56.7, 24.4, 27.9, 39.3, 66.5, 29.4, 24.6, 25.4, 56.3, 41.5, 172.7, 33.0, 172.7 |
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MASS_CHART |
M+= 264, m/z= 222, 152, 138, 110, 97, 83 |
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참고문헌 |
· NK. Hart et al., Aust. J. Chem., 21, 1619, 1968(ir,ms)
· K. Asres et al., J. Nat. Prod., 49, 117, 1986(nmr)
· Y. Yamada et al., Agric. Biol. Chem., 34, 1536, 1970
· SI. Goldberg et al., J. Org. Chem., 35, 242, 1970
· E. Wenkert et al., J. Org. Chem., 35, 515, 1970
· WJ. Keller, Phytochemistry, 19, 2233, 1980
· I. Murakoshi et al., Phytochemistry, 20, 1725, 1981
· WJ. Keller, J. Nat. Prod., 44, 357, 1981
· JP. Michael et al., Tetrahedron, 48, 10211, 1992 |
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