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 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

Glaudine

다른이름들 

O,N-Dimethylporphyroxine O,N-Dimethylpapaverrubine (6-alpha-8-beta)-2,3,8-Trimethoxy-16-methyl-10,11-[methylenebis(oxy)]rheadan

함유 천연물 

Papaver somniferum L.[양귀비(Yang-gwi-bi)](앵속각(罌粟殼))

분 자 식 

C₂₂H₂₅NO₆

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

399.448

녹 는 점 

103-105°C Heptane

굴 절 율 

[α]24 D = +455° (C 0.5,CHCl3)

UV_CHART 

(λmax, nm) (MeOH):235(4.19), 285(3.94)

HNMR_CHART 

(CDCl3) δ:5.21(2H, d, 9, H1), 4.10(1H, d, 9, H2), 5.78(1H, s, H14), 6.69(1H, s, H6), 7.37(1H, s, H9), 6.81, 7.08(2H, ABq, 8, H10,11), 2.26(3H, s, NMe), 3.70(3H, s, 14-OMe), 5.94, 6.05(2H, dd, 1, 3, OCH2O), 3.89(6H, s, OMe)

MASS_CHART 

M+= 399, m/z= 384, 220, 206, 193(100), 192

참고문헌 

· JD. Phillipson et al., Phytochemistry, 19, 2189, 1980(pmr,ms) · S. Pfeifer, Pharmazie, 19, 724, 1964(uv) · AI. Gray et al., Planta Med., 41, 2, 1, 1981(uv,ms) · M. Shamma et al., Chem. Comm., 212, 1968 · V. Preininger et al., Planta Med., 41, 119, 1981